| 2012-02-05 |
| 00:00 | Andujar/Berlocq vs Souza/Zeballos |
| 11:00 | Stefanie Voegele vs Samantha Stosur |
| 12:00 | Maria Sharapova vs Carla Suarez Navarro |
| 12:00 | Sabine Lisicki vs Petra Kvitova |
| 12:15 | Timea Bacsinszky vs Jarmila Gajdosova |
| 13:00 | Mahut/Roger Vasselin vs Hanley/J Murray |
| 13:00 | Dominika Cibulkova vs Pauline Parmentier |
| 13:15 | Svetlana Kuznetsova vs Silvia Soler Espinosa |
| 13:15 | Julia Goerges vs Iveta Benesova |
| 13:30 | Bacsinszky/Sadikovic vs Dellacqua/Dokic |
| 14:15 | Daniela Hantuchova vs Virginie Razzano |
| 14:30 | Makarova/Petrova vs Llagostera Vives/Parra Sant |
| 14:30 | Yanina Wickmayer vs Jelena Jankovic |
| 14:30 | Groenefeld/Kerber vs Hradecka/Z Strycova |
| 15:30 | Tomas Berdych vs Gael Monfils |
| 15:30 | Cibulkova/Hantuchova vs Cornet/Mladenovic |
| 15:45 | Kirsten Flipkens vs Bojana Jovanovski |
| 16:00 | Francesca Schiavone vs Kateryna Bondarenko |
| 17:00 | Hendler/Van Uytvanck vs Jankovic/Krunic |
| 17:00 | Mikhail Youzhny vs Lukas Lacko |
| 17:15 | Sara Errani vs Lesia Tsurenko |
| 18:15 | Dodig/Pavic vs Baghdatis/Youzhny |
| 18:30 | Errani/Vinci vs Beygelzimer/Savchuk |
| 19:00 | Serena Williams vs Anastasiya Yakimova |
| 20:15 | Christina McHale vs Olga Govortsova |
| 21:30 | Huber/V Williams vs Azarenka/Govortsova |
